Department of Chemistry, Tallinn University of Technology, Tallinn, Estonia.
Electrophoresis. 2012 Jan;33(1):196-210. doi: 10.1002/elps.201100357. Epub 2011 Nov 30.
This article is the seventh in a series examining biannually the methodological developments in the field of CE analysis of inorganic species and covers relevant documents published between January 2009 and December 2010. Following an analysis of the significant accomplishments that have impacted the field in two recent years, a survey of advances in general CE methodology is presented. Subsequently, several notable trends that can be perceived in this well-established field are discussed: the continuing rise of ME and consequent development of suitable detection techniques, most notably contactless conductivity detection, the constant pace of advances in speciation analysis, and an increase in non-analytical CE applications to study complexation and (bio)transformation reactions of metal analytes. A range of recently emerged multi-detection designs, ICP-MS interface devices, and separation systems, for which outpacing work has been conducted, are also brought into focus.
本文是系列研究的第七篇，每两年对无机物种 CE 分析领域的方法进展进行一次审查，涵盖了 2009 年 1 月至 2010 年 12 月期间发表的相关文献。在分析了过去两年中对该领域产生重大影响的成果之后，本文介绍了 CE 一般方法学的进展。随后，讨论了在这个成熟领域中可以察觉到的一些显著趋势：ME 的持续兴起以及相应的合适检测技术的发展，尤其是非接触式电导检测技术；形态分析的不断进步；以及非分析 CE 应用于研究金属分析物的络合和（生物）转化反应的应用日益增多。本文还重点介绍了一系列最近出现的多检测设计、ICP-MS 接口装置和分离系统，这些领域的工作进展迅速。
