过渡金属催化反应中的自由基？过渡金属催化的自由基反应？——无论如何都是一种富有成效的相互作用：第2部分。第8族和第9族元素的自由基催化
Radicals in transition metal catalyzed reactions? transition metal catalyzed radical reactions? - a fruitful interplay anyway: part 2. Radical catalysis by group 8 and 9 elements.
作者信息
Jahn Ullrich
机构信息
Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo namesti 2, 16610, Prague 6, Czech Republic.
出版信息
Top Curr Chem. 2012;320:191-322. doi: 10.1007/128_2011_285.
PMID:22143610
Abstract
This review summarizes the current status of transition metal catalyzed reactions involving radical intermediates in organic chemistry. This part focuses on radical-based methods catalyzed by group 8 and group 9 metal complexes. Reductive and redox-neutral coupling methods catalyzed by low-valent metal complexes as well as catalytic oxidative C-C bond formations are reviewed.
摘要
本综述总结了有机化学中涉及自由基中间体的过渡金属催化反应的现状。本部分重点介绍由第8族和第9族金属配合物催化的基于自由基的方法。综述了低价金属配合物催化的还原和氧化还原中性偶联方法以及催化氧化C-C键的形成。
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