Jahn Ullrich
Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo namesti 2, 16610, Prague 6, Czech Republic.
Top Curr Chem. 2012;320:323-451. doi: 10.1007/128_2011_288.
This review summarizes the current status of transition metal catalyzed reactions involving radical intermediates in organic chemistry. This part focuses on radical-based methods catalyzed by group 10 and group 11 metal complexes. Reductive and redox-neutral C-C bond formations catalyzed by low-valent metal complexes as well as catalytic oxidative methods are reviewed. Catalytic processes which rely on the combination of two metal complexes are also covered.
本综述总结了有机化学中涉及自由基中间体的过渡金属催化反应的现状。这部分重点介绍了由第10族和第11族金属配合物催化的基于自由基的方法。综述了低价金属配合物催化的还原和氧化还原中性C-C键形成以及催化氧化方法。还涵盖了依赖于两种金属配合物组合的催化过程。