School of Chemistry, University of Hyderabad, Hyderabad, 500 046, India.
Nanoscale. 2012 Jan 21;4(2):343-59. doi: 10.1039/c1nr11313e. Epub 2011 Dec 7.
A major part of contemporary nanomaterials research is focused on metal and semiconductor nanoparticles, constituted of extended lattices of atoms or ions. Molecular nanoparticles assembled from small molecules through non-covalent interactions are relatively less explored but equally fascinating materials. Their unique and versatile characteristics have attracted considerable attention in recent years, establishing their identity and status as a novel class of nanomaterials. Optical characteristics of molecular nanoparticles capture the essence of their nanoscale features and form the basis of a variety of applications. This review describes the advances made in the field of fabrication of molecular nanoparticles, the wide spectrum of their optical and nonlinear optical characteristics and explorations of the potential applications that exploit their unique optical attributes.
当代纳米材料研究的一个主要部分集中在由原子或离子的扩展晶格组成的金属和半导体纳米粒子上。通过非共价相互作用组装的小分子纳米粒子是相对较少探索但同样引人入胜的材料。它们独特而多样的特性近年来引起了相当大的关注,确立了它们作为一类新型纳米材料的身份和地位。分子纳米粒子的光学特性捕捉到了它们纳米尺度特征的本质,并为各种应用奠定了基础。本文综述了分子纳米粒子的制备领域的进展,以及它们广泛的光学和非线性光学特性,并探讨了利用其独特光学特性的潜在应用。