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[由几种双甲基丙烯酸缩水甘油酯单体制备用于贴面冠的透明热固性树脂(作者译)]

[Preparation of clear thermosetting resin for veneered crown from several bisMEPP monomers (author's transl)].

作者信息

Tanaka T, Nakabayashi N, Masuhara E

出版信息

Shika Rikogaku Zasshi. 1978 Jul;19(47):168-72.

PMID:282384
Abstract

The whitish translucent shade of a thermosetting resin cured from a mixture of a 2,2-Bis (p-methacryloxy (ethoxy)1-2 phenyl)-propane monomer and PMMA pearls makes it difficult to reconstruct a shade of the natural tooth. The attempt to improve the transparency of the mixed polymer was made in this study. Varying the molecular weight of BisMEPP monomer, PMMA polymer and curing temperature, cured specimens were prepared and their transparency was measured with a spectrophotometer. The results obtained are as follows. 1) In any molecular weight of PMMA, BisMEPP with 2.3 to 3.3 average number of ethylene oxide linkage showed the highest transpalency on the specimen. 2) With increasing the curing temperature, transpalency of the specimens made from BisME4.0 PP increased. With another molecular of BisMEPP, transpalency of the cured specimens showed the highest transpalency at the curing temperature of 120 degrees C. 3) With increasing the molecular weight of PMMA, the transpalency increased.

摘要

由2,2-双(对甲基丙烯酰氧基(乙氧基)-1-2苯基)丙烷单体与聚甲基丙烯酸甲酯(PMMA)微珠的混合物固化而成的热固性树脂呈现出的微白色半透明色调,使得再现天然牙齿的色调变得困难。本研究尝试提高混合聚合物的透明度。通过改变双甲基丙烯酸乙氧基苯基丙烷(BisMEPP)单体、聚甲基丙烯酸甲酯(PMMA)聚合物的分子量以及固化温度,制备了固化试样,并用分光光度计测量了它们的透明度。所得结果如下:1)在任何聚甲基丙烯酸甲酯(PMMA)分子量下,平均环氧乙烷键数为2.3至3.3的双甲基丙烯酸乙氧基苯基丙烷(BisMEPP)在试样上显示出最高的透明度。2)随着固化温度升高,由双甲基丙烯酸4.0乙氧基苯基丙烷(BisME4.0PP)制成的试样的透明度增加。对于双甲基丙烯酸乙氧基苯基丙烷(BisMEPP)的其他分子,固化试样在120℃的固化温度下显示出最高的透明度。3)随着聚甲基丙烯酸甲酯(PMMA)分子量的增加,透明度增加。

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