• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Stereocontrol in intramolecular hydrosilylation of allyl and homoallyl alcohols: a new approach to the stereoselective synthesis of 1,3-diol skeletons.

作者信息

Tamao K, Nakajima T, Sumiya R, Arai H, Higuchi N, Ito Y

出版信息

J Am Chem Soc. 1986 Sep 1;108(19):6090-3. doi: 10.1021/ja00279a097.

DOI:10.1021/ja00279a097
PMID:22175405
Abstract
摘要

相似文献

1
Stereocontrol in intramolecular hydrosilylation of allyl and homoallyl alcohols: a new approach to the stereoselective synthesis of 1,3-diol skeletons.烯丙醇和高烯丙醇分子内硅氢化反应中的立体控制：一种立体选择性合成1,3 - 二醇骨架的新方法。
J Am Chem Soc. 1986 Sep 1;108(19):6090-3. doi: 10.1021/ja00279a097.
2
Pd(OAc)2/P(cC6H11)3-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation.醋酸钯/三环己基膦催化芳基卤化物与高烯丙醇通过逆烯丙基化反应进行的烯丙基化反应。
J Am Chem Soc. 2007 Apr 11;129(14):4463-9. doi: 10.1021/ja067372d. Epub 2007 Mar 21.
3
Intramolecular syn and anti hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted allylic alcohols.分子内顺式和反式硅氢化反应以及硅辅助交叉偶联：三取代烯丙醇的高度区域和立体选择性合成。
Org Lett. 2003 Apr 3;5(7):1119-22. doi: 10.1021/ol0342002.
4
Synthesis of (arylalkenyl)silanes by palladium-catalyzed regiospecific and stereoselective allyl transfer from silyl-substituted homoallyl alcohols to aryl halides.通过钯催化实现硅基取代的高烯丙醇向芳基卤化物的区域特异性和立体选择性烯丙基转移来合成（芳基烯基）硅烷。
J Am Chem Soc. 2007 Oct 24;129(42):12650-1. doi: 10.1021/ja0755111. Epub 2007 Sep 29.
5
Nickel-catalyzed allylation of allyl carbonates with homoallyl alcohols via retro-allylation providing 1,5-hexadienes.镍催化碳酸烯丙酯与高烯丙醇通过逆烯丙基化反应生成1,5-己二烯。
Org Lett. 2008 Apr 17;10(8):1629-32. doi: 10.1021/ol800335v. Epub 2008 Mar 21.
6
Highly diastereoselective hydrostannylation of allyl and homoallyl alcohols with dibutyl(trifluoromethanesulfoxy)stannane.烯丙醇和高烯丙醇与二丁基（三氟甲磺氧基）锡烷的高度非对映选择性氢化锡化反应。
J Am Chem Soc. 2005 Jul 6;127(26):9366-7. doi: 10.1021/ja052245n.
7
Petasis Borono-Mannich reaction and allylation of carbonyl compounds via transient allyl boronates generated by palladium-catalyzed substitution of allyl alcohols. an efficient one-pot route to stereodefined alpha-amino acids and homoallyl alcohols.通过钯催化烯丙醇取代反应生成的瞬态烯丙基硼酸酯实现羰基化合物的Petasis硼-曼尼希反应和烯丙基化反应。一种立体定向合成α-氨基酸和高烯丙醇的高效一锅法路线。
J Am Chem Soc. 2007 Nov 7;129(44):13723-31. doi: 10.1021/ja074917a. Epub 2007 Oct 12.
8
Deprotection of homoallyl ((h)Allyl) derivatives of phenols, alcohols, acids, and amines.酚、醇、酸和胺的高烯丙基（(h)烯丙基）衍生物的脱保护。
J Org Chem. 2009 Apr 3;74(7):2854-7. doi: 10.1021/jo900012z.
9
Palladium-catalyzed allylation of aryl halides with homoallyl alcohols bearing a trisubstituted double bond: application to chirality transfer from hydroxylated carbon to benzylic one.钯催化带有三取代双键的偕丙基醇与芳基卤化物的烯丙基化反应：手性从羟化碳原子向苄位碳原子转移的应用。
J Org Chem. 2010 Jul 2;75(13):4337-43. doi: 10.1021/jo100857d.
10
Intramolecular coupling of allyl carboxylates with allyl stannanes and allyl silanes: a new type of reductive elimination reaction?烯丙基羧酸盐与烯丙基锡烷和烯丙基硅烷的分子内偶联：一种新型的还原消除反应？
Chemistry. 2002 Aug 16;8(16):3620-8. doi: 10.1002/1521-3765(20020816)8:16<3620::AID-CHEM3620>3.0.CO;2-P.

引用本文的文献

1
Catalytic enantioselective synthesis of benzocyclobutenols and cyclobutanols a sequential reduction/C-H functionalization.苯并环丁醇和环丁醇的催化对映选择性合成——一种连续还原/C-H官能团化反应。
Chem Sci. 2021 Jul 5;12(31):10598-10604. doi: 10.1039/d1sc02119b. eCollection 2021 Aug 11.
2
Synthesis of cyclic 1,3-diols as scaffolds for spatially directed libraries.环状1,3 -二醇作为空间定向文库支架的合成。
Org Biomol Chem. 2016 May 14;14(18):4299-303. doi: 10.1039/c6ob00598e.
3
Hydroxyl-directed stereoselective diboration of alkenes.
烯烃的羟基导向立体选择性双硼化反应
J Am Chem Soc. 2014 Jul 2;136(26):9264-7. doi: 10.1021/ja504228p. Epub 2014 Jun 24.
4
Enantio- and diastereoselective synthesis of N-acetyl dihydrotetrafibricin methyl ester.对映选择性和非对映选择性合成 N-乙酰二氢四呋辛甲酯。
J Am Chem Soc. 2013 Apr 10;135(14):5340-3. doi: 10.1021/ja401918r. Epub 2013 Mar 26.
5
B(C6F5)3-promoted tandem silylation and intramolecular hydrosilylation: diastereoselective synthesis of oxasilinanes and oxasilepanes.B(C6F5)3 促进的串联硅烷化和分子内硅氢化反应：氧硅杂螺环烷和氧硅杂环戊烷的非对映选择性合成。
Org Lett. 2010 Nov 5;12(21):4772-5. doi: 10.1021/ol1018757.
6
Stereoselective synthesis of syn,syn- and syn,anti-1,3,5-triols via intramolecular hydrosilylation of substituted pent-3-en-1,5-diols.通过取代的戊-3-烯-1,5-二醇的分子内硅氢化反应立体选择性合成顺式、顺式-和顺式、反式-1,3,5-三醇。
Org Lett. 2009 Jul 2;11(13):2932-5. doi: 10.1021/ol9009877.
7
Discovery and synthetic applications of novel silicon-carbon bond cleavage reactions based on the coordination number change of organosilicon compounds.基于有机硅化合物配位数变化的新型碳硅键裂解反应的发现及其合成应用
Proc Jpn Acad Ser B Phys Biol Sci. 2008;84(5):123-33. doi: 10.2183/pjab.84.123.