模板合成、后合成金属交换和卟啉包封的金属有机材料的性质。
Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material.
机构信息
Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, Florida 33620, USA.
出版信息
J Am Chem Soc. 2012 Jan 18;134(2):924-7. doi: 10.1021/ja209643b. Epub 2011 Dec 28.
Reaction of biphenyl-3,4',5-tricarboxylate (H(3)BPT) and CdCl(2) in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd(6)(BPT)(4)Cl(4)(H(2)O)(4)]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.
联苯-3,4',5-三甲酸（H(3)BPT）与 CdCl(2)在meso-四（N-甲基-4-吡啶基）卟啉四对甲苯磺酸盐（TMPyP）的存在下反应，得到微孔金属-有机材料 porph@MOM-10，其包含包裹在阴离子 Cd(II) 羧酸盐骨架中的 CdTMPyP 阳离子，[Cd(6)(BPT)(4)Cl(4)(H(2)O)(4)]。Porph@MOM-10 是一种多功能平台，可进行交换，作为一系列具有永久孔隙率和多相催化活性的 porph@MOMs 的母体。
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