Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Jinan 250100, China.
J Hazard Mater. 2012 Feb 15;203-204:53-61. doi: 10.1016/j.jhazmat.2011.11.095. Epub 2011 Dec 8.
The preparation, characteristics and mechanisms of sintered bricks manufactured by Yellow River silt and red mud were studied. The sintering shrinkage, weight loss on ignition, water absorption and compressive strength were tested to determine the optimum preparation condition. Sintering mechanisms were discussed through linear regression analysis. Crystalline components of raw materials and bricks were analyzed by X-ray diffraction. Leaching toxicity of raw materials and bricks were measured according to sulphuric acid and nitric acid method. Radiation safety of the sintered bricks was characterized by calculating internal exposure index and external exposure index. The results showed that at the chosen best parameters (red mud content of 40%, sintering temperature of 1050°C and sintering time of 2h), the best characteristics of sintered bricks could be obtained. The weight loss on ignition of sintered bricks was principally caused by the removal of absorbed water and crystal water. The sintering shrinkage of sintered bricks mainly depended on sodium compounds and iron compounds of red mud. The sintering process made some components of raw materials transform into other crystals having better thermostability. Besides, the leaching toxicity and radioactivity index of sintered bricks produced under the optimum condition were all below standards.
研究了黄河淤泥和赤泥制备烧结砖的制备、特性和机理。通过测试烧结收缩率、烧失量、吸水率和抗压强度来确定最佳的制备条件。通过线性回归分析讨论了烧结机理。通过 X 射线衍射分析了原材料和砖的晶体成分。根据硫酸和硝酸法测量了原材料和砖的浸出毒性。通过计算内照射指数和外照射指数来表征烧结砖的辐射安全性。结果表明,在所选择的最佳参数(赤泥含量 40%、烧结温度 1050°C 和烧结时间 2h)下,可获得烧结砖的最佳特性。烧结砖的烧失量主要是由于去除了吸附水和结晶水。烧结砖的烧结收缩主要取决于赤泥中的钠化合物和铁化合物。烧结过程使原材料的一些成分转化为其他具有更好热稳定性的晶体。此外,在最佳条件下生产的烧结砖的浸出毒性和放射性指数均低于标准。