呋喃甾烷的醚转移介导的 E 环开裂和立体选择性“氧化还原”修饰。
Transetherification-mediated E-ring opening and stereoselective "Red-Ox" modification of furostan.
机构信息
The Division of Medicinal Chemistry, College of Pharmacy, University of Texas at Austin, Austin, TX 78712, United States.
出版信息
Steroids. 2012 Feb;77(3):276-81. doi: 10.1016/j.steroids.2011.12.015. Epub 2011 Dec 17.
Abstract
We have developed a novel E-ring opening method for furostan, and applied it to prepare D-ring modified steroids, which can be used to synthesize cephalostatin analogs.
摘要
我们开发了一种新型的呋甾烷 E 环开裂方法，并将其应用于制备 D 环修饰的甾体，可用于合成头孢菌素类似物。
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