Xiao Yunyun, Shen Xiaoping, Li Yizhi
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1734. doi: 10.1107/S1600536811046800. Epub 2011 Nov 9.
In the title compound, [Fe(C(12)H(8)N(3)O(2))(2)][Fe(C(12)H(8)N(3)O(2))(CN)(3)]·H(2)O, the Fe(3+) ions in the cation and anion each lie in a slightly distorted octa-hedral coordination environment. The solvent water mol-ecule is disordered over three positions with occupancies of 0.401 (7), 0.322 (7) and 0.277 (6). The water content was confirmed by thermogravimetric data.
在标题化合物[Fe(C₁₂H₈N₃O₂)₂][Fe(C₁₂H₈N₃O₂)(CN)₃]·H₂O中,阳离子和阴离子中的Fe³⁺离子各自处于略微扭曲的八面体配位环境中。溶剂水分子在三个位置上无序分布,占有率分别为0.401 (7)、0.322 (7)和0.277 (6)。通过热重数据证实了水含量。