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高氯酸双[N-(2-吡啶甲酰基)吡啶-2-甲脒基]铁(III)甲醇溶剂合物

Bis[N-(2-pyridylcarbon-yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate.

作者信息

Wu Dayu

机构信息

Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Teachers College, Anqing, 246011 Anhui, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):m1340. doi: 10.1107/S1600536809040549.

DOI:10.1107/S1600536809040549
PMID:21578096
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2971300/
Abstract

In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl-carbon-yl)pyridine-2-carboximidate (bpca) ligands and exhib-its a distorted octa-hedral coordination by six bpca N atoms. A classical O-H⋯O hydrogen bond exists between the methanol solvent mol-ecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5-400 K.

摘要

在标题配合物[Fe(C₁₂H₈N₃O₂)₂]ClO₄·CH₃OH中，铁(III)离子被两个三齿的N-(2-吡啶甲酰基)吡啶-2-甲脒(bpca)配体所环绕，并通过六个bpca N原子呈现出扭曲的八面体配位。在甲醇溶剂分子和高氯酸根阴离子之间存在经典的O-H⋯O氢键。磁化率测量表明该配合物在5 - 400 K的温度范围内处于低自旋态。

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