Chygorin Eduard N, Petrusenko Svitlana R, Kokozay Volodymyr N, Smal Yuri O, Omelchenko Irina V, Shishkin Oleg V
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1563-4. doi: 10.1107/S1600536811041523. Epub 2011 Oct 22.
The title compound, [Mn(C(3)H(7)NO)(6)][Fe(2)Cl(6)O], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes with Schiff base ligands using manganese powder and FeCl(3)·6H(2)O as starting materials. In the Fe(2)OCl(6) anion, the O atom and the Fe atom occupy positions with site symmetry [Formula: see text] and 3, respectively, resulting in a linear Fe-O-Fe angle and a staggered conformation. The octa-hedrally surrounded cation (site symmetry [Formula: see text]) and the Fe(2)Cl(6)O anion are alternately stacked along [001].
标题化合物[Mn(C₃H₇NO)₆][Fe₂Cl₆O]是在尝试以锰粉和FeCl₃·6H₂O为起始原料合成含席夫碱配体的异金属配合物时意外得到的产物。在[Fe₂OCl₆]²⁻阴离子中，O原子和Fe原子分别占据点群对称性为[化学式：见原文]和3的位置，形成线性的Fe - O - Fe角和交错构象。八面体配位的阳离子（点群对称性[化学式：见原文]）和[Fe₂Cl₆O]²⁻阴离子沿[001]方向交替堆积。
