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（3,6-二甲氧基-萘-2-基）（2,4,6-三甲基-苯基）甲酮

(3,6-Dimeth-oxy-naphthalen-2-yl)(2,4,6-trimethyl-phen-yl)methanone.

作者信息

Muto Toyokazu, Sasagawa Kosuke, Okamoto Akiko, Oike Hideaki, Yonezawa Noriyuki

机构信息

Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, 2-24-16 Naka-machi, Koganei, Tokyo 184-8588, Japan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o3062. doi: 10.1107/S1600536811042401. Epub 2011 Oct 29.

DOI:10.1107/S1600536811042401
PMID:22220071
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3247453/
Abstract

In the title compound, C(22)H(22)O(3), the dihedral angle between the naphthalene ring system and the benzene ring is 79.95 (5)°. The bridging carbonyl C-C(=O)-C group makes dihedral angles of 24.21 (7) and 82.43 (8)°, respectively, with the naphthalene ring system and the benzene ring. In the crystal, weak inter-molecular C-H⋯O inter-actions link mol-ecules into chains parallel to the c axis.

摘要

在标题化合物C₂₂H₂₂O₃中，萘环体系与苯环之间的二面角为79.95（5）°。桥连羰基C-C(=O)-C基团与萘环体系和苯环分别形成24.21（7）°和82.43（8）°的二面角。在晶体中，弱的分子间C-H⋯O相互作用将分子连接成平行于c轴的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20dc/3247453/b7a387d5b4df/e-67-o3062-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20dc/3247453/3d87be6ae5c3/e-67-o3062-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20dc/3247453/b7a387d5b4df/e-67-o3062-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20dc/3247453/3d87be6ae5c3/e-67-o3062-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20dc/3247453/b7a387d5b4df/e-67-o3062-fig2.jpg

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