Muto Toyokazu, Sasagawa Kosuke, Okamoto Akiko, Oike Hideaki, Yonezawa Noriyuki
Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology, 2-24-16 Naka-machi, Koganei, Tokyo 184-8588, Japan.
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o906. doi: 10.1107/S1600536812008112. Epub 2012 Feb 29.
In the title compound, C(29)H(25)ClO(4), the dihedral angle between the benzene rings of the 2,4,6-trimethyl-benzoyl group and the 4-chloro-benzoyl group is 65.19 (9)°. The dihedral angles between the naphthalene ring system and the benzene rings of the 2,4,6-trimethyl-benzoyl group and the 4-chloro-benzoyl group are 85.66 (8) and 69.48 (8)°, respectively. In the crystal, two types of inter-molecular C-H⋯O inter-actions and an intra-molecular C-H⋯O inter-action are observed. Moreover, there is a short intra-molecular C=O⋯C=O contact of 2.614 (2) Å between the benzoyl substituents.
在标题化合物C₂₉H₂₅ClO₄中，2,4,6-三甲基苯甲酰基的苯环与4-氯苯甲酰基的苯环之间的二面角为65.19(9)°。萘环体系与2,4,6-三甲基苯甲酰基的苯环以及4-氯苯甲酰基的苯环之间的二面角分别为85.66(8)°和69.48(8)°。在晶体中，观察到两种分子间C—H⋯O相互作用和一种分子内C—H⋯O相互作用。此外，苯甲酰基取代基之间存在2.614(2) Å的短分子内C=O⋯C=O接触。
