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通过简单的湿化学方法合成及表征氧化铜纳米线

Synthesis and characterization of CuO nanowires by a simple wet chemical method.

作者信息

Ethiraj Anita Sagadevan, Kang Dae Joon

机构信息

BK21 Physics Research Division, Department of Energy Science, Institute of Basic Science, Sungkyunkwan University, 300 Cheoncheon-dong, Jangan-gu, Suwon, 440-746, South Korea.

出版信息

Nanoscale Res Lett. 2012 Jan 5;7(1):70. doi: 10.1186/1556-276X-7-70.

Abstract

We report a successful synthesis of copper oxide nanowires with an average diameter of 90 nm and lengths of several micrometers by using a simple and inexpensive wet chemical method. The CuO nanowires prepared via this method are advantageous for industrial applications which require mass production and low thermal budget technique. It is found that the concentration and the quantity of precursors are the critical factors for obtaining the desired one-dimensional morphology. Field emission scanning electron microscopy images indicate the influence of thioglycerol on the dispersity of the prepared CuO nanowires possibly due to the stabilization effect of the surface caused by the organic molecule thioglycerol. The Fourier transform infrared spectrum analysis, energy dispersive X-ray analysis, X-ray diffraction analysis, and X-ray photoemission spectrum analysis confirm clearly the formation of a pure phase high-quality CuO with monoclinic crystal structure.

摘要

我们报道了一种通过简单且低成本的湿化学方法成功合成平均直径为90纳米、长度为几微米的氧化铜纳米线。通过该方法制备的氧化铜纳米线有利于需要大规模生产和低热预算技术的工业应用。发现前驱体的浓度和数量是获得所需一维形态的关键因素。场发射扫描电子显微镜图像表明,硫代甘油可能由于有机分子硫代甘油对表面的稳定作用而对所制备的氧化铜纳米线的分散性产生影响。傅里叶变换红外光谱分析、能量色散X射线分析、X射线衍射分析和X射线光电子能谱分析清楚地证实了具有单斜晶体结构的纯相高质量氧化铜的形成。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4b3/3283496/a8866c2fe8c4/1556-276X-7-70-1.jpg

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