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具有易面各向异性的伪四面体钴(II)配合物中的缓慢磁弛豫。

Slow magnetic relaxation in a pseudotetrahedral cobalt(II) complex with easy-plane anisotropy.

机构信息

Department of Chemistry, University of California, Berkeley, California 94720, USA.

出版信息

Chem Commun (Camb). 2012 Apr 25;48(33):3927-9. doi: 10.1039/c2cc16430b. Epub 2012 Jan 5.

DOI:10.1039/c2cc16430b
PMID:22222273
Abstract

A pseudotetrahedral cobalt(II) complex with a positive axial zero-field splitting parameter of D = 12.7 cm(-1), as determined by high-field EPR spectroscopy, is shown to exhibit slow magnetic relaxation under an applied dc field.

摘要

高场 EPR 光谱学测定，具有正轴向零场分裂参数 D = 12.7 cm(-1)的拟四面体型钴(II)配合物在施加直流场时表现出缓慢的磁弛豫。

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