Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
Chemphyschem. 2012 Mar;13(4):923-6. doi: 10.1002/cphc.201100833. Epub 2012 Jan 13.
Clearly visible: A water-soluble and highly fluorescent perylenediimide is synthesized via ruthenium-catalyzed alkylation with outstanding yields. For the first time, the possibility to use phosphonate derivatives in a Murai-type reaction is demonstrated.
通过钌催化的烷基化反应合成了一种水溶性和高荧光性的苝二酰亚胺,产率优异。首次证明了在 Murai 型反应中使用膦酸酯衍生物的可能性。