不对称二芳基乙烯作为分子密码锁，通过 Cu2+ 和 CN- 的配位作用，具有可调的光致变色和荧光性能。
Unsymmetrical diarylethenes as molecular keypad locks with tunable photochromism and fluorescence via Cu2+ and CN- coordinations.
机构信息
Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai 200237, China.
出版信息
Chem Commun (Camb). 2012 Feb 18;48(15):2095-7. doi: 10.1039/c2cc16942h. Epub 2012 Jan 13.
PMID:22246172
Abstract
New unsymmetrical diarylethenes were synthesized and their photochromic and fluorescent properties are tailored by Cu(2+) and CN(-) coordinations. A novel molecular logic keypad lock is constructed based on the fluorescence emission changes by the inputs of UV/visible irradiation, Cu(2+) and CN(-).
摘要
新的非对称二噻烯被合成出来，并通过 Cu(2+) 和 CN(-) 的配位作用来调整其光致变色和荧光性质。基于紫外线/可见光辐照、Cu(2+) 和 CN(-) 的输入引起的荧光发射变化，构建了一种新颖的分子逻辑键盘锁。
Zotero 插件