基于 p-型和 n-型聚（金属 1,1,2,2-乙撑四硫代二羧酸酯）的有机热电材料和器件。
Organic thermoelectric materials and devices based on p- and n-type poly(metal 1,1,2,2-ethenetetrathiolate)s.
机构信息
Beijing National Laboratory for Molecular Sciences, Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China.
出版信息
Adv Mater. 2012 Feb 14;24(7):932-7. doi: 10.1002/adma.201104305. Epub 2012 Jan 17.
PMID:22250047
Abstract
A series of metal coordination polymers containing 1,1,2,2-ethenetetrathiolate (ett) linking bridge (poly[Ax(M-ett)]) are synthesized. The Seebeck coefficients of these conducting materials are high, and vary according to the center metals and counter cations. The TE device fabricated demonstrates the great potentials of these materials for TE applications.
摘要
一系列含有 1,1,2,2-乙二硫醇（ett）连接桥的金属配位聚合物（poly[Ax(M-ett)]）被合成。这些导电材料的塞贝克系数较高，且根据中心金属和抗衡阳离子的不同而变化。所制备的 TE 器件展示了这些材料在 TE 应用中的巨大潜力。
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