铁催化的脂肪族羧酸脱羰反应生成α-烯烃。
Iron-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to α-olefins.
机构信息
Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan.
出版信息
Chem Commun (Camb). 2012 Mar 4;48(19):2552-4. doi: 10.1039/c2cc18093f. Epub 2012 Jan 30.
PMID:22286391
Abstract
The catalytic decarbonylation reaction of aliphatic carboxylic acids can be carried out in the presence of an iron complex, and it proceeds smoothly to give α-olefins with high selectivity.
摘要
脂肪族羧酸的催化脱羰反应可以在铁络合物的存在下进行，反应顺利进行，高选择性地得到α-烯烃。
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