三氟甲磺酸根作为抗衡阴离子的铁(III)卟啉催化末端芳基和脂肪族烯烃的选择性氧化为醛。
Selective oxidation of terminal aryl and aliphatic alkenes to aldehydes catalyzed by iron(III) porphyrins with triflate as a counter anion.
机构信息
Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China.
出版信息
Chem Commun (Camb). 2011 Oct 21;47(39):10963-5. doi: 10.1039/c1cc13574k. Epub 2011 Sep 12.
PMID:21909523
Abstract
[Fe(Por)CF(3)SO(3)] (Por = porphyrin dianion) can efficiently catalyze selective oxidation of terminal aryl alkenes and aliphatic alkenes to aldehydes in good to high yields under mild conditions.
摘要
[Fe(Por)CF3SO3]（Por=卟啉二阴离子）在温和条件下可以高效地催化末端芳基烯烃和脂肪族烯烃的选择性氧化反应，以高产率得到相应的醛。
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