Christian-Albrechts-Universität zu Kiel, Institut für Anorganische Chemie, Max-Eyth-Str. 2, 24118 Kiel, Germany.
Dalton Trans. 2012 Apr 14;41(14):4164-71. doi: 10.1039/c2dt12005d. Epub 2012 Jan 30.
A new family of Al-based MOFs denoted as CAU-3 (CAU = Christian-Albrechts-Universität) was discovered in the solvothermal system Al(3+)/aryldicarboxylic acid/NaOH/methanol by applying high-throughput-methods. The three compounds reported in this article [Al(2)(OCH(3))(4)BDC], [Al(2)(OCH(3))(4)BDC-NH(2)] and[Al(2)(OCH(3))(4)NDC] (BDC = 1,4-benzenedicarboxylate; NDC = 2,6-naphtalenedicarboxylate) are all based on the same unprecedented inorganic building unit Al(12)(OCH(3))(24), which is a dodecameric cyclic aluminium-methanolate-cluster. The material CAU-3-NDC was found to exhibit the highest surface area as well as the highest micropore volume of all Al-based MOFs reported until now.
一种新的基于 Al 的 MOF 家族被命名为 CAU-3（CAU = 克里斯蒂安-阿尔布雷希特大学），是在溶剂热体系 Al(3+)/芳基二羧酸/NaOH/甲醇中通过高通量方法发现的。本文报道的三种化合物 [Al(2)(OCH(3))(4)BDC]、[Al(2)(OCH(3))(4)BDC-NH(2)] 和 [Al(2)(OCH(3))(4)NDC]（BDC = 1,4-苯二甲酸；NDC = 2,6-萘二甲酸）均基于相同的前所未有的无机建筑单元 Al(12)(OCH(3))(24)，这是一个十二聚体环状铝甲醇簇。发现材料 CAU-3-NDC 具有迄今为止报道的所有基于 Al 的 MOF 中最高的比表面积和最高的微孔体积。
