Institute of Inorganic Chemistry, Christian-Albrechts-Universität Kiel, Max-Eyth-Straße 2, 24118 Kiel, Germany.
Chem Commun (Camb). 2012 Oct 4;48(76):9486-8. doi: 10.1039/c2cc34909d.
The new Al-based metal-organic framework [Al(13)(OH)(27)(H(2)O)(6)(BDC-NH(2))(3)Cl(6)(C(3)H(7)OH)(6)] denoted CAU-6 (CAU = Christian-Albrechts-Universität) was solvothermally synthesized in 2-propanol and was thoroughly characterized. The framework structure exhibits a unique column-shaped inorganic building unit, which is based on stacked, corner-sharing Al(13)-clusters. The compound exhibits unprecedented hydrophilicity for metal-organic frameworks.
新型基于铝的金属有机骨架[Al(13)(OH)(27)(H(2)O)(6)(BDC-NH(2))(3)Cl(6)(C(3)H(7)OH)(6)]，表示为 CAU-6（CAU = 克里斯蒂安-阿尔布雷希特大学），在异丙醇中通过溶剂热法合成，并进行了彻底的表征。该骨架结构呈现出独特的柱状无机建筑单元，基于堆叠的、角共享的 Al(13)-簇。该化合物表现出金属有机骨架前所未有的亲水性。
