生物相关的 N-杂环芳烃与烯烃的脱氢 Heck 偶联：荧光核心骨架的发现。
Dehydrogenative Heck coupling of biologically relevant N-heteroarenes with alkenes: discovery of fluorescent core frameworks.
机构信息
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064, PR China.
出版信息
Chem Commun (Camb). 2012 Mar 18;48(23):2864-6. doi: 10.1039/c2cc17557f. Epub 2012 Feb 3.
PMID:22302073
Abstract
A Pd/Cu-catalyzed dehydrogenative Heck coupling is established that allows direct alkenylation of various biologically relevant N-heteroarenes with alkenes. The resulting π-extended alkenylated N-heteroarenes exhibit interesting fluorescent properties and have proven to be potentially useful fluorescent probes for bioimaging.
摘要
建立了一种 Pd/Cu 催化的脱氢 Heck 偶联反应，可实现各种生物相关的 N-杂芳烃与烯烃的直接烯基化。得到的π-扩展的烯基化 N-杂芳烃具有有趣的荧光性质，并已被证明是潜在有用的生物成像荧光探针。
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