State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P.R. China.
Org Lett. 2012 Feb 17;14(4):1158-61. doi: 10.1021/ol300107v. Epub 2012 Feb 3.
An approach is developed for the synthesis of bisbenzannelated spiro[5,5]ketals via a catalytic relay reaction cascade involving a new cyclo-etherification, which is prompted by fluoride and catalyzed by the hypoiodite species generated in situ from irradiative aerobic oxidation of an iodide ion formed in the former step of the reaction cascade.
开发了一种通过涉及新环醚化的催化接力反应级联合成双苯并annelated 螺[5.5]缩酮的方法，该方法由氟化物引发，并由反应级联的前一步中形成的碘化物离子的有氧氧化原位生成的次碘酸盐物种催化。
