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纳米 TiO2 负载活性炭(负载 TiO2/AC/MW)存在下水溶液中甲基橙染料的微波降解。

Microwave degradation of methyl orange dye in aqueous solution in the presence of nano-TiO2-supported activated carbon (supported-TiO2/AC/MW).

机构信息

College of Environment, Liaoning University, Shenyang 110036, People's Republic of China.

出版信息

J Hazard Mater. 2012 Mar 30;209-210:271-7. doi: 10.1016/j.jhazmat.2012.01.021. Epub 2012 Jan 20.

Abstract

In this study, nano-TiO(2)-supported activated carbon (TiO(2)/AC) was developed for the microwave (MW) degradation of an azo dye, methyl orange (MO), selected as a model contaminant in aqueous solution. The effects of selected process parameters such as supported TiO(2) content, MW irradiation time, initial MO concentration, catalyst dose, and solution pH on the degradation were assessed in detail. The results showed that the supported TiO(2) on AC could be excited resulting in the production of hydroxyl radical (OH) in aqueous solution under MW irradiation, which significantly enhanced the performance of AC/MW process for the degradation of MO. Also, the supported-TiO(2)/AC displayed higher catalytic activity than AC alone under MW irradiation. By comparison, the supported-TiO(2)/AC/MW process exhibited several advantages, including high degradation rate, short irradiation time, no residual intermediates and no secondary pollution. Hence, it shows to be a promising technology for the destruction of organic contaminants in dye treatment applications.

摘要

在这项研究中,开发了负载纳米二氧化钛的活性炭(TiO2/AC),用于微波(MW)降解偶氮染料甲基橙(MO),MO 被选为水溶液中的模型污染物。详细评估了负载 TiO2 含量、MW 辐照时间、初始 MO 浓度、催化剂剂量和溶液 pH 等选定工艺参数对降解的影响。结果表明,负载在 AC 上的 TiO2 在 MW 辐照下可被激发,导致水溶液中产生羟基自由基(OH),这显著增强了 AC/MW 工艺降解 MO 的性能。此外,在 MW 辐照下,负载 TiO2/AC 比单独的 AC 具有更高的催化活性。相比之下,负载 TiO2/AC/MW 工艺具有许多优点,包括高降解率、短辐照时间、无残留中间体和无二次污染。因此,它有望成为染料处理应用中破坏有机污染物的一种有前途的技术。

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