使用负载在 MOF-5 上的钯纳米粒子实现芳基碘代物的常压氨基羰基化反应。
Atmospheric pressure aminocarbonylation of aryl iodides using palladium nanoparticles supported on MOF-5.
机构信息
Institute of Chemical and Engineering Sciences (ICES), 8 Biomedical Grove, #07-01 Neuros, Singapore 138665.
出版信息
Chem Commun (Camb). 2012 Feb 7;48(12):1805-7. doi: 10.1039/c2cc16808a.
PMID:22338700
Abstract
An efficient amide synthesis by atmospheric pressure aminocarbonylation using palladium nanoparticles supported on MOF-5 is reported. Interestingly, only 0.5 wt% palladium loading was required to achieve high yields. The catalyst is recyclable and offers negligible palladium leaching.
摘要
报道了一种使用负载在 MOF-5 上的钯纳米粒子在常压下进行酰胺合成的有效方法。有趣的是，仅需 0.5wt%的钯负载量即可实现高产率。该催化剂可回收利用，钯浸出可忽略不计。
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