Ghaemi Akbar, Dadkhah Zohreh, Ng Seik Weng, Tiekink Edward R T
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m210. doi: 10.1107/S1600536812002796. Epub 2012 Jan 31.
The asymmetric unit of the title compound, {[Pb(C(9)H(6)NO)(2)]·0.5C(3)H(7)NO}(n), comprises Pb(quinolate)(2) and half a dimethyl-formamide mol-ecule (which is disordered about a centre of inversion). The quinolate ligands N,O-chelate to a Pb(II) ion and simultaneously bridge a neighbouring Pb(II) ion to form a polymeric chain along [100] comprising Pb-linked Pb(2)O(2) distorted rhombi. These chains pack to form a square grid, with the channels thus defined occupied by the disordered solvent mol-ecules.
标题化合物{[Pb(C₉H₆NO)₂]·0.5C₃H₇NO}ₙ的不对称单元包含二喹啉酸铅和半个二甲基甲酰胺分子(该分子在一个反演中心处无序)。喹啉酸配体通过N、O与Pb(II)离子螯合,并同时桥连相邻的Pb(II)离子,沿着[100]方向形成一条包含由Pb连接的Pb₂O₂扭曲菱形的聚合物链。这些链堆积形成一个方形网格,如此定义的通道被无序的溶剂分子占据。