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采用大籽南瓜叶提取物合成银纳米粒子及其在光催化降解中的应用

Phytosynthesis of silver nanoparticles using Coccinia grandis leaf extract and its application in the photocatalytic degradation.

机构信息

Department of Biotechnology, CSIR-Central Leather Research Institute, Chennai, India.

出版信息

Colloids Surf B Biointerfaces. 2012 Jun 1;94:226-30. doi: 10.1016/j.colsurfb.2012.01.040. Epub 2012 Feb 2.

Abstract

Silver nanoparticles were successfully synthesized from aqueous AgNO(3) through a simple green route using the leaf extract of Coccinia grandis as a reducing as well as capping agent. The results obtained from UV-vis spectrum, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and Fourier-transform infra red spectroscopy (FTIR) and high-resolution transmission electron microscopy (HRTEM) revealed that the biosynthesis of silver nanoparticles were in the size range of 20-30 nm and is crystallized in face centered cubic symmetry. Further, the thermal stability of nanoparticles was studied using thermo gravimetric analyzer (TGA) and differential scanning calorimeter (DSC). Photocatalytic property of the Ag nanoparticles was investigated by degradation of Coomassie Brilliant Blue G-250 under UV light. The results show that Ag nanoparticles have suitable activity for the degradation of Coomassie Brilliant Blue G-250.

摘要

采用简单的绿色路线,使用大籽南瓜的叶提取物作为还原剂和稳定剂,成功地从水溶液中的 AgNO(3) 中合成了银纳米粒子。紫外可见光谱、X 射线衍射 (XRD)、扫描电子显微镜 (SEM)、能谱仪 (EDS)、傅里叶变换红外光谱 (FTIR) 和高分辨率透射电子显微镜 (HRTEM) 的结果表明,银纳米粒子的生物合成尺寸范围在 20-30nm 之间,呈面心立方对称性结晶。此外,还使用热重分析仪 (TGA) 和差示扫描量热仪 (DSC) 研究了纳米粒子的热稳定性。通过在紫外光下降解考马斯亮蓝 G-250 研究了 Ag 纳米粒子的光催化性能。结果表明,Ag 纳米粒子对考马斯亮蓝 G-250 的降解具有适宜的活性。

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