手性聚合诱导的手性光学活性的产生与反转：源于柠檬烯手性的二烷基聚硅烷的对称破缺聚集。
Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality.
机构信息
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192, Japan.
出版信息
Chem Commun (Camb). 2012 Jul 7;48(53):6636-8. doi: 10.1039/c2cc17845a. Epub 2012 Feb 24.
PMID:22361997
Abstract
We observed the emergence and inversion of chiroptical handedness in three chiroptically silent dialkylpolysilanes during aggregation in limonene-methanol-THF tersolvents.
摘要
我们在柠檬烯-甲醇-THF 三元溶剂中观察到三个手性沉默的二烷基聚硅烷在聚集过程中手性的出现和反转。
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