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大花凌霄花中的新环烯醚萜。

Novel iridoids from the flowers of Campsis grandiflora.

机构信息

College of Pharmacy, Chungbuk National University, Cheongju 361-763, Korea.

出版信息

Arch Pharm Res. 2012 Feb;35(2):327-32. doi: 10.1007/s12272-012-0213-9. Epub 2012 Feb 28.

Abstract

A non-glycosidic iridoid, campsinol (1), and two iridoid glucosides, 7-O-(Z)-p-coumaroylcachineside V (2) and 7-O-(E)-p-coumaroylcachineside I (3), were isolated from the fresh flowers of Campsis grandiflora along with five known iridoid glycosides, ixoroside (4), campsiside (5), cachineside I (6), 5-hydroxycampenoside (7), and 5-hydroxycampsiside (8), and two known phenylpropanoid glycosides, acteoside (9) and leucosceptoside A (10). The structures of these compounds were determined based on the NMR and Mass spectroscopic data and other chemical evidences.

摘要

从凌霄花的鲜花中分离得到了一种非糖苷类环烯醚萜,campsinol(1),以及两种环烯醚萜糖苷,7-O-(Z)-对香豆酰鸡纳苷 V(2)和 7-O-(E)-对香豆酰鸡纳苷 I(3),此外还分离得到了 5 种已知的环烯醚萜糖苷,ixoroside(4)、camposide(5)、cachineside I(6)、5-羟基筋骨草苷(7)和 5-羟基筋骨草苷(8),以及 2 种已知的苯丙素糖苷,acteoside(9)和leucosceptoside A(10)。这些化合物的结构是根据 NMR 和质谱数据以及其他化学证据确定的。

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