Department of Chemical and Bimolecular Engineering, Tulane University, New Orleans, Louisiana 70118, United States.
Langmuir. 2012 Apr 3;28(13):5737-42. doi: 10.1021/la204040p. Epub 2012 Mar 22.
Recently, there has been significant interest in developing dry adhesives mimicking the gecko adhesive system, which offers several advantages compared to conventional pressure-sensitive adhesives. Specifically, gecko adhesive pads have anisotropic adhesion properties; the adhesive pads (spatulae) stick strongly when sheared in one direction but are non-adherent when sheared in the opposite direction. This anisotropy property is attributed to the complex topography of the array of fine tilted and curved columnar structures (setae) that bear the spatulae. In this study, we present an easy, scalable method, relying on conventional and unconventional techniques, to incorporate tilt in the fabrication of synthetic polymer-based dry adhesives mimicking the gecko adhesive system, which provides anisotropic adhesion properties. We measured the anisotropic adhesion and friction properties of samples with various tilt angles to test the validity of a nanoscale tape-peeling model of spatular function. Consistent with the peel zone model, samples with lower tilt angles yielded larger adhesion forces. The tribological properties of the synthetic arrays were highly anisotropic, reminiscent of the frictional adhesion behavior of gecko setal arrays. When a 60° tilt sample was actuated in the gripping direction, a static adhesion strength of ~1.4 N/cm(2) and a static friction strength of ~5.4 N/cm(2) were obtained. In contrast, when the dry adhesive was actuated in the releasing direction, we measured an initial repulsive normal force and negligible friction.
最近,人们对模仿壁虎黏附系统的干性粘合剂的开发产生了浓厚的兴趣,与传统的压敏粘合剂相比,这种系统具有几个优势。具体来说,壁虎黏附垫具有各向异性的黏附特性;当在一个方向上剪切时,黏附垫(匙状突)会强烈黏附,但在相反方向上剪切时则不黏附。这种各向异性特性归因于排列成阵列的精细倾斜和弯曲柱状结构(刚毛)的复杂形貌,这些结构承载着匙状突。在这项研究中,我们提出了一种简单、可扩展的方法,依赖于常规和非常规技术,在制造模仿壁虎黏附系统的基于合成聚合物的干性粘合剂时引入倾斜,从而提供各向异性的黏附特性。我们测量了具有不同倾斜角度的样品的各向异性黏附力和摩擦力,以测试匙状突功能的纳米级胶带剥离模型的有效性。与剥离区模型一致,倾斜角度较低的样品产生了更大的黏附力。合成阵列的摩擦学性能具有高度各向异性,类似于壁虎刚毛阵列的摩擦黏附行为。当 60°倾斜样品在夹持方向上被驱动时,获得了约 1.4 N/cm(2)的静态黏附强度和约 5.4 N/cm(2)的静态摩擦强度。相比之下,当干性粘合剂在释放方向上被驱动时,我们测量到初始的排斥法向力和可忽略的摩擦力。