State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
Molecules. 2012 Mar 6;17(3):2812-22. doi: 10.3390/molecules17032812.
An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [(PPh(3))AuCl]/AgOTf as catalyst has been developed. The reaction between 1,3-dicarbonyl compounds and primary amines was carried out under solvent-free conditions with low catalyst loading in good to excellent yields at room temperature.
已开发出一种使用 [(PPh(3))AuCl]/AgOTf 作为催化剂的高效合成 β-烯胺酮和 β-烯氨基酯的方法。在无溶剂条件下，在室温下，使用低催化剂负载量，通过 1,3-二羰基化合物和伯胺之间的反应，以良好至优异的收率得到产物。
