钯催化的各种胺与氯甲基萘和氯甲基蒽衍生物的胺化反应。
Palladium-catalyzed amination of chloromethylnaphthalene and chloromethylanthracene derivatives with various amines.
机构信息
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China.
出版信息
J Am Chem Soc. 2012 Mar 28;134(12):5492-5. doi: 10.1021/ja300164d. Epub 2012 Mar 15.
PMID:22409404
Abstract
Palladium-catalyzed amination of chloromethylnaphthalene and chloromethylanthracene derivatives to produce naphthylamines and anthrylamines in satisfactory to good yields has been developed. The unprecedented amination reactions proceeded smoothly under mild conditions in the presence of Pd(PPh(3))(4) as a catalyst.
摘要
开发了钯催化的氯甲基萘和氯甲基蒽衍生物的胺化反应，以令人满意至良好的收率得到萘胺和蒽胺。在温和条件下，在 Pd(PPh(3))(4)作为催化剂的存在下，进行了前所未有的胺化反应，反应顺利进行。
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