• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

链状聚[[(异喹啉-κN)(三苯基膦-κP)铜(I)]-μ-硫氰酸根-κN:S]

catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thio-cyanato-κN:S].

作者信息

Li Jian-Bao, Zhou Li-Li, Wu Man-Hua, Jin Qiong-Hua, Zhang Cun-Lin

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m283-4. doi: 10.1107/S1600536812004837. Epub 2012 Feb 10.

DOI:10.1107/S1600536812004837
PMID:22412430
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3297240/
Abstract

In the title coordination compound, Cu(NCS)(C(9)H(7)N)(C(18)H(15)P), the Cu(I) atom is tetra-hedrally coordinated by one N atom from an isoquinoline ligand, one P atom from a triphenyl-phospane ligand, and one N and one S atom from two thio-cyanate anions. The thio-cyanide anions bridge the Cu(I) atoms into a chain along [100]. π-π inter-actions between the pyridine and benzene rings of the isoquinoline ligands connect the chains [centroid-to-centroid distance = 3.722 (3) Å].

摘要

在标题配位化合物[Cu(NCS)(C₉H₇N)(C₁₈H₁₅P)]ₙ中，Cu(I)原子由异喹啉配体的一个N原子、三苯基膦配体的一个P原子以及两个硫氰酸根阴离子的一个N原子和一个S原子呈四面体配位。硫氰酸根阴离子将Cu(I)原子沿[100]方向桥连形成一条链。异喹啉配体的吡啶环和苯环之间的π-π相互作用连接这些链[质心到质心距离 = 3.722 (3) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31ce/3297240/9b429d6a636c/e-68-0m283-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31ce/3297240/7e5489ce436b/e-68-0m283-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31ce/3297240/9b429d6a636c/e-68-0m283-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31ce/3297240/7e5489ce436b/e-68-0m283-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31ce/3297240/9b429d6a636c/e-68-0m283-fig2.jpg

相似文献

1
catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thio-cyanato-κN:S].链状聚[[(异喹啉-κN)(三苯基膦-κP)铜(I)]-μ-硫氰酸根-κN:S]
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m283-4. doi: 10.1107/S1600536812004837. Epub 2012 Feb 10.
2
catena-Poly[[(2,2'-bipyridine-κN,N')copper(I)]-μ-cyanido-κC:N-[(2,2'-bipyridine-κN,N')copper(I)]-μ-thio-cyanato-κS:N].链状聚[[(2,2'-联吡啶-κN,N')铜(I)]-μ-氰基-κC:N-[(2,2'-联吡啶-κN,N')铜(I)]-μ-硫氰酸根-κS:N]
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 20;64(Pt 12):m1576. doi: 10.1107/S1600536808037756.
3
catena-Poly[[(8-amino-quinoline-κN,N')cadmium]-di-μ-thio-cyanato-κN:S;κS:N-[(8-amino-quinoline-κN,N')cadmium]-di-μ-chlorido].链状聚[[(8-氨基喹啉-κN,N')镉]-二-μ-硫氰酸根合-κN:S;κS:N-[(8-氨基喹啉-κN,N')镉]-二-μ-氯合]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m3. doi: 10.1107/S1600536811051373. Epub 2011 Dec 3.
4
Poly[(μ(2)-3,6-di-4-pyridyl-1,2,4,5-tetra-zine)(μ(2)-thio-cyanato)copper(I)].聚[（μ(2)-3,6-二-4-吡啶基-1,2,4,5-四嗪）（μ(2)-硫氰酸根）铜（I）]
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m217. doi: 10.1107/S1600536810001431.
5
catena-Poly[[[N,N'-bis-(3-methoxy-benzyl-idene)ethyl-enediamine]copper(I)]-μ-thio-cyanato-κN:S].链状聚[[[N,N'-双-(3-甲氧基-亚苄基)乙二胺]铜(I)]-μ-硫氰酸根合-κN:S]
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 13;65(Pt 1):m70. doi: 10.1107/S1600536808041925.
6
Poly[μ-4,4'-bipyridine-κN:N'-μ-thio-cyanato-κN:S-copper(I)].聚[μ-4,4'-联吡啶-κN:N'-μ-硫氰酸根合-κN:S-铜(I)]
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 18;64(Pt 11):m1424-5. doi: 10.1107/S1600536808033175.
7
catena-Poly[[(5-phenyl-2,2'-bipyridine-κN,N')copper(I)]-μ-thio-cyanido-κN:S].链状聚[[(5-苯基-2,2'-联吡啶-κN,N')铜(I)]-μ-硫氰酸根-κN:S]
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m165. doi: 10.1107/S1600536812000682. Epub 2012 Jan 18.
8
catena-Poly[[bis-(pyridine-κN)cadmium]-di-μ(2)-thio-cyanato-κN:S;κS:N].链状聚[[双（吡啶-κN）镉]-二-μ（2）-硫氰酸根合-κN：S；κS：N]
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m481. doi: 10.1107/S1600536811009871. Epub 2011 Mar 26.
9
Bis(2-chloro-1,10-phenanthroline-κN,N')(thio-cyanato-κN)zinc (2-chloro-1,10-phenanthroline-κN,N')tris-(thio-cyanato-κN)zincate.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m202. doi: 10.1107/S1600536812002280. Epub 2012 Jan 25.
10
Poly[bis(μ(3)-thio-cyanato-κN:S:S')(μ(2)-thio-cyanato-κN:S)(4'-p-tolyl-2,2':6',2''-terpyridine-κN,N',N'')cadmium(II)silver(I)].聚[双(μ(3)-硫氰酸根合-κN:S:S')(μ(2)-硫氰酸根合-κN:S)(4'-对甲苯基-2,2':6',2''-三联吡啶-κN,N',N'')镉(II)银(I)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):m1313-4. doi: 10.1107/S160053681003744X.

本文引用的文献

1
Bis(2,2'-bi-1H-imidazole-κN,N)bis-(dimethyl sulfoxide-κO)copper(II) bis-(tetra-fluoridoborate).双（2,2'-联-1H-咪唑-κN,N）双（二甲亚砜-κO）铜（II）双（四氟硼酸盐）
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 18;66(Pt 9):m1124-5. doi: 10.1107/S1600536810031922.
2
catena-Poly[silver(I)-bis-[μ-bis-(diphenyl-phosphino)methane-κP:P']-μ-thio-cyanato-κS:S-silver(I)-μ-thio-cyanato-κS:N].链状聚[银（I）-双-[μ-双-（二苯基膦基）甲烷-κP:P']-μ-硫氰酸根-κS:S-银（I）-μ-硫氰酸根-κS:N]
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1237-8. doi: 10.1107/S1600536810035622.
3
A short history of SHELX.
SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.