Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
Chem Commun (Camb). 2012 May 4;48(35):4214-6. doi: 10.1039/c2cc18156h. Epub 2012 Mar 22.
A highly chemo-, regio-selective, and efficient palladium-catalyzed deamidative arylation of azoles with arylamides, as an aryl metal equivalent, has been developed. The reaction proceeds smoothly to generate the corresponding products in good yields via a tandem decarbonylation-C-H activation.
发展了一种高化学选择性、区域选择性和高效的钯催化唑类与芳酰胺(作为芳基金属等价物)的脱酰胺芳基化反应。该反应通过串联脱羰-C-H 活化,以良好的收率顺利进行,生成相应的产物。