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紫细菌和假单胞菌从电子废物中生物浸出金属

Metals bioleaching from electronic waste by Chromobacterium violaceum and Pseudomonads sp.

机构信息

Department of Biotechnology and Bioinformatics, Jaypee University of Information Technology, Waknaghat, Solan, Himachal Pradesh, India.

出版信息

Waste Manag Res. 2012 Nov;30(11):1151-9. doi: 10.1177/0734242X12437565. Epub 2012 Mar 27.

Abstract

These days, electronic waste needs to be taken into consideration due to its materials content, but due to the heterogeneity of the metals present, reprocessing of electronic waste is quite limited. The bioleaching of metals from electronic waste was investigated by using cyanogenic bacterial strains (Chromobacterium violaceum, Pseudomonas aeruginosa and Pseudomonas fluorescens). A two-step bioleaching process was followed under cyanide-forming conditions for maximum metals mobilization. Both single and mixed cultures of cyanogenic bacteria were able to mobilize metals from electronic waste with different efficiencies. In all the flasks in which high metal mobilizations were observed, the consequent biomass productions were also high. Pseudomonas aeruginosa was applied in the bioleaching process for the first time and this achieved its bioleaching ability of mobilization of metals from electronic waste. Chromobacterium violaceum as a single culture and a mixture of C. violaceum and P. aeruginosa exhibited maximum metal mobilization. Chromobacterium violaceum was capable of leaching more than 79, 69, 46, 9 and 7% of Cu, Au, Zn, Fe and Ag, respectively at an electronic waste concentration of 1% w/v. Moreover, the mixture of C. violaceum and P. aeruginosa exhibited metals leaching of more than 83, 73, 49, 13 and 8% of total Cu, Au, Zn, Fe, and Ag, respectively. Precious metals were mobilized through bioleaching which might be considered as an industrial application for recycling of electronic waste in the near future.

摘要

如今,由于电子废弃物的材料含量,需要对其加以考虑,但由于其中存在的金属具有异质性,因此对电子废弃物的再处理非常有限。本研究采用产氰细菌(紫色色杆菌、铜绿假单胞菌和荧光假单胞菌)来研究从电子废弃物中浸出金属。在形成氰化物的条件下采用两步生物浸出法,以实现最大金属迁移。产氰细菌的单一和混合培养都能够以不同的效率从电子废物中迁移金属。在所有观察到高金属迁移的培养瓶中,随后的生物量产量也很高。铜绿假单胞菌首次应用于生物浸出过程中,实现了其从电子废物中浸出金属的生物浸出能力。单一培养的紫色色杆菌和紫色色杆菌与铜绿假单胞菌的混合物表现出最大的金属迁移能力。在 1%w/v 的电子废物浓度下,紫色色杆菌分别能够浸出超过 79%、69%、46%、9%和 7%的 Cu、Au、Zn、Fe 和 Ag。此外,紫色色杆菌与铜绿假单胞菌的混合物分别能够浸出超过 83%、73%、49%、13%和 8%的总 Cu、Au、Zn、Fe 和 Ag。通过生物浸出可以迁移贵金属,这可能被视为未来电子废物回收的工业应用。

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