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采用有机化学浸出法从废弃印刷电路板中进行经济高效且环保的铜回收。

Cost-effective and eco-friendly copper recovery from waste printed circuit boards using organic chemical leaching.

作者信息

Nagarajan Navashree, Panchatcharam Parthasarathy

机构信息

Department of Electronics and Communication Engineering, CMR Institute of Technology, Bengaluru, 560037, India.

出版信息

Heliyon. 2023 Feb 17;9(3):e13806. doi: 10.1016/j.heliyon.2023.e13806. eCollection 2023 Mar.

Abstract

Electronic waste generation is indeed a global concern; therefore, appropriate management and recycling are becoming highly significant. Printed circuit boards (PCBs) are significant portion of e-waste; contains a large number of valuable metals, rendering this material an important recovery resource. Among all other metals, the high Copper concentration of PCB residues, which is often ten times higher than that of rich-content rocks, makes these residues an appealing secondary source of Cu recovery. The primary goal of this study is to develop a simple and economical method for recovering Cu from waste PCBs. To leach metals, a combination of citric acid, acetic acid, and hydrogen peroxide (HO) was utilized. The influence of systemic factors such as citric acid concentration, acetic acid concentration, and HO concentration on Cu leaching process was investigated. The results proved that the combination of citric acid, acetic acid, and HO has increased the leaching efficiency of copper. More copper was dissolved when leaching with 0.5-1.5 M citric acid, 2.5-7.5%, and 2.5-7.5% HO at 30 °C; however the individual acids produces less amount of Cu such as 26.86 ppm, 22.33 ppm, and 6.28 ppm whereas, high amount of Cu is obtained from the leaching solution containing 1 M citric acid, 5% acetic acid and 5% HO with 325.89 ppm respectively. Thus, the combination of these acids and can be used as standardized method for leaching of Cu. These findings suggest that organic acids can replace inorganic acids as eco-friendly lixiviants for waste management.

摘要

电子垃圾的产生确实是一个全球关注的问题;因此,适当的管理和回收变得非常重要。印刷电路板(PCBs)是电子垃圾的重要组成部分;含有大量有价值的金属,使这种材料成为重要的回收资源。在所有其他金属中,PCB残渣中高浓度的铜,通常比富铜岩石中的铜含量高十倍,这使得这些残渣成为有吸引力的铜回收二次来源。本研究的主要目标是开发一种从废弃印刷电路板中回收铜的简单经济的方法。为了浸出金属,使用了柠檬酸、醋酸和过氧化氢(HO)的组合。研究了柠檬酸浓度、醋酸浓度和HO浓度等系统因素对铜浸出过程的影响。结果证明,柠檬酸、醋酸和HO的组合提高了铜的浸出效率。在30℃下用0.5-1.5M柠檬酸、2.5-7.5%醋酸和2.5-7.5%HO浸出时,溶解的铜更多;然而,单独的酸产生的铜量较少,如26.86ppm、22.33ppm和6.28ppm,而从分别含有1M柠檬酸、5%醋酸和5%HO的浸出溶液中获得的铜量较高,为325.89ppm。因此,这些酸的组合可作为浸出铜的标准化方法。这些发现表明,有机酸可以替代无机酸作为废物管理的环保浸出剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/39ae/9988466/678c5be946ba/ga1.jpg

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