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粉煤灰稳定城市污泥对马尼拉草生长和重金属迁移的影响。

Effects of municipal sewage sludge stabilized by fly ash on the growth of Manilagrass and transfer of heavy metals.

机构信息

Department of Environmental Science and Engineering, College of Chemical Engineering, Huaqiao University, Xiamen, China.

出版信息

J Hazard Mater. 2012 May 30;217-218:58-66. doi: 10.1016/j.jhazmat.2012.02.065. Epub 2012 Mar 3.

Abstract

A greenhouse experiment was carried out to evaluate the feasibility of using an artificial soil for cultivation of Manilagrass. The transfer and transformation of heavy metals in the artificial soil-Manilagrass system were discussed at the same time. The results showed that fly ash-sludge indicated a positive effect on the growth of Manilagrass. The pots with 14% sludge and 6% fly ash mixture had the highest yield and nutrient concentrations of Manilagrass. With the increasing application of coal fly ash, the concentrations of Ni, Zn, Mn, Sb and Cu in Manilagrass decreased significantly, while Pb, V and Ti increased. Otherwise, the concentrations of Cd, As, Cr, Co, and Fe did not show a remarkable change. Except for Sb, the values of bio-concentration factor of heavy metals in Manilagrass were all below 1.0 after treated by the fly ash-sludge treatment, decreased as Sb>Ni>Zn>Cu>Pb>Mn>Co=Cr>Cd>Fe=V>Ti>As in an average for all treatments. Compared to the contrast check, the proportions of heavy metals in exchangeable, reducible and oxidizable fractions increased. Manilagrass could be used to reduce the eco-toxicity and bioavailability of Ti, V, Mn, Co, Cr and Cd in fly ash-sludge amended soil.

摘要

采用温室盆栽试验研究了人工土壤栽培马尼拉草的可行性,同时探讨了重金属在人工土壤-马尼拉草系统中的迁移转化规律。结果表明,粉煤灰-污泥对马尼拉草的生长有明显的促进作用,当污泥添加量为 14%、粉煤灰添加量为 6%时马尼拉草的生物量最高,养分浓度也最大。随着粉煤灰施用量的增加,马尼拉草中 Ni、Zn、Mn、Sb 和 Cu 含量显著降低,而 Pb、V 和 Ti 含量增加。此外,Cd、As、Cr、Co 和 Fe 含量没有明显变化。除 Sb 外,经粉煤灰-污泥处理后,马尼拉草中重金属的生物浓缩系数均小于 1.0,平均值大小顺序为 Sb>Ni>Zn>Cu>Pb>Mn>Co=Cr>Cd>Fe=V>Ti>As。与对照相比,重金属的可交换态、还原态和氧化态比例增加。马尼拉草可以降低粉煤灰-污泥改良土壤中 Ti、V、Mn、Co、Cr 和 Cd 的生态毒性和生物可利用性。

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