从螺环内酰胺混合物到区域异构体纯的 5-和 6-罗丹明：一种基于化学计量比的策略。
From spirolactam mixtures to regioisomerically pure 5- and 6-rhodamines: a chemodosimeter-inspired strategy.
机构信息
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China.
出版信息
Org Lett. 2012 Apr 20;14(8):2014-7. doi: 10.1021/ol300523m. Epub 2012 Apr 3.
PMID:22471975
Abstract
Inspired by the ring-open reaction of rhodamine spriolactams as typical chemodosimeters, a general strategy is proposed to conveniently and efficiently synthesize isomerically pure 5- and 6-R-tetramethylrhodamine on a larger scale.
摘要
受罗丹明螺环内酰胺的开环反应作为典型化学比色计的启发，提出了一种通用策略，以便方便、有效地在较大规模上合成具有异构纯的 5- 和 6-R-四甲基罗丹明。
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