Department of Mining and Metallurgical Engineering, National Technical University of Athens 9, Athens, Greece.
J Hazard Mater. 2012 May 30;217-218:1-10. doi: 10.1016/j.jhazmat.2012.03.052. Epub 2012 Mar 27.
Aluminium salt slag (also known as aluminium salt cake), which is produced by the secondary aluminium industry, is formed during aluminium scrap/dross melting and contains 15-30% aluminium oxide, 30-55% sodium chloride, 15-30% potassium chloride, 5-7% metallic aluminium and impurities (carbides, nitrides, sulphides and phosphides). Depending on the raw mix the amount of salt slag produced per tonne of secondary aluminium ranges from 200 to 500 kg. As salt slag has been classified as toxic and hazardous waste, it should be managed in compliance with the current legislation. Its landfill disposal is forbidden in most of the European countries and it should be recycled and processed in a proper way by taking the environmental impact into consideration. This paper presents a review of the aluminium salt slag chemical and mineralogical characteristics, as well as various processes for metal recovery, recycling of sodium and potassium chlorides content back to the smelting process and preparation of value added products from the final non metallic residue.
铝盐渣(也称为铝盐饼)是由再生铝工业生产的,在铝废料/浮渣熔炼过程中形成,含有 15-30%的氧化铝、30-55%的氯化钠、15-30%的氯化钾、5-7%的金属铝和杂质(碳化物、氮化物、硫化物和磷化物)。每吨再生铝产生的铝盐渣量取决于原料混合物,范围为 200 至 500 千克。由于铝盐渣已被归类为有毒和危险废物,因此应按照现行法规进行管理。在大多数欧洲国家,禁止将其填埋处置,应考虑环境影响,以适当的方式对其进行回收和处理。本文综述了铝盐渣的化学和矿物学特性,以及各种金属回收工艺,将氯化钠和氯化钾含量回收回熔炼过程,并从最终的非金属残渣中制备有附加值的产品。