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比较来自芬兰和波兰的越橘 Vaccinium vitis-idaea 的浆果和叶子中的三萜含量。

Comparison of the triterpenoid content of berries and leaves of lingonberry Vaccinium vitis-idaea from Finland and Poland.

机构信息

Department of Plant Biochemistry, Faculty of Biology, University of Warsaw, ul. Miecznikowa 1, 02-096 Warszawa, Poland.

出版信息

J Agric Food Chem. 2012 May 16;60(19):4994-5002. doi: 10.1021/jf300375b. Epub 2012 May 7.

Abstract

Triterpenoid compounds extracted from fruits and leaves of lingonberry ( Vaccinium vitis-idaea L.) collected in Finland and Poland were identified and quantitated by GC-MS/FID. The main lingonberry triterpenoid profile consisted of α-amyrin, β-amyrin, betulin, campesterol, cycloartanol, erythrodiol, fern-7-en-3β-ol, friedelin, lupeol, sitosterol, stigmasterol, stigmasta-3,5-dien-7-one, swert-9(11)-en-3β-ol, taraxasterol, urs-12-en-29-al, uvaol, oleanolic acid, and ursolic acid. To our knowledge, this is the first thorough description of triterpenoid compounds in this species. Ursolic acid was identified as a principal triterpene in lingonberry fruit. The influence of geographical origin on the level of individual triterpenoid compounds was examined, and considerable variations in triterpenoid profile between berries and leaves obtained from the two locations were observed. The most striking difference concerned the occurrence of fernenol and taraxasterol, which were found to be the major triterpenol in lingonberry leaves of Finnish and Polish origin, respectively.

摘要

从芬兰和波兰采集的越橘(Vaccinium vitis-idaea L.)的果实和叶子中提取的三萜类化合物,通过 GC-MS/FID 进行了鉴定和定量分析。越橘的主要三萜类物质组成包括 α-香树脂醇、β-香树脂醇、桦木醇、菜油甾醇、环阿尔廷醇、赤藓醇、蕨烯-3β-醇、羽扇豆醇、齐墩果酸、豆甾醇、β-谷甾醇、麦角甾-3,5-二烯-7-酮、熊果烷-9(11)-烯-3β-醇、蒲公英甾醇、12-齐墩果烯-29-醇、乌苏酸和熊果酸。据我们所知,这是对该物种三萜类化合物的首次全面描述。在越橘果实中鉴定出熊果酸为主要三萜。考察了地理起源对个别三萜类化合物水平的影响,发现在来自两个地点的浆果和叶子之间存在三萜类物质组成的显著差异。最显著的差异涉及到 fernenol 和 taraxasterol 的存在,它们分别是芬兰和波兰越橘叶中主要的三萜醇。

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