当更大更好时：杂配位碱土金属配合物催化的活化烯烃的分子间氢官能化反应。
When bigger is better: intermolecular hydrofunctionalizations of activated alkenes catalyzed by heteroleptic alkaline Earth complexes.
机构信息
Institut des Sciences Chimiques de Rennes, UMR CNRS-Université de Rennes, Campus de Beaulieu, France.
出版信息
Angew Chem Int Ed Engl. 2012 May 14;51(20):4943-6. doi: 10.1002/anie.201200364. Epub 2012 Apr 11.
PMID:22492421
Abstract
New alkaline-earth amido complexes catalyze the regioselective intermolecular hydroamination (see scheme; Ae=alkaline earth) and hydrophosphination of styrene and isoprene with unprecedented activities. The catalytic performances increased linearly with the size of the metal.
摘要
新型碱土金属酰胺配合物可催化苯乙烯和异戊二烯的区域选择性分子间氨氢化（见方案；Ae=碱土金属）和膦氢化，具有前所未有的活性。催化性能随金属尺寸线性增加。
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