Department of Polymer Science and Engineering, Graduate School of Science and Engineering, Yamagata University, 4-3-16, Jonan, Yonezawa 992-8510, Japan.
Macromol Rapid Commun. 2012 Jul 13;33(13):1090-107. doi: 10.1002/marc.201100887. Epub 2012 Apr 17.
This review summarizes recent advances in the design and synthesis of amino-acid-based block copolymers by reversible addition-fragmentation chain transfer (RAFT) polymerization of amino-acid-bearing monomers. We will mainly focus on stimuli-responsive block copolymers, such as pH-, thermo-, and dual-stimuli-responsive block copolymers, and self-assembled block copolymers, including amphiphilic and double-hydrophilic block copolymers having tunable chiroptical properties. We will also highlight recent results in RAFT synthesis of amino-acid-based copolymers having various properties, such as catalytic and optoelectronic properties, cross-linked block copolymer micelles, unimolecular micelles, and organic-inorganic hybrids.
本文综述了通过氨基酸单体的可逆加成-断裂链转移（RAFT）聚合来设计和合成氨基酸基嵌段共聚物的最新进展。我们将主要关注刺激响应性嵌段共聚物，如 pH、温度和双重刺激响应性嵌段共聚物，以及自组装嵌段共聚物，包括具有可调手性性质的两亲性和双亲性嵌段共聚物。我们还将重点介绍 RAFT 合成具有各种性质的氨基酸基共聚物的最新结果，如催化和光电性质、交联嵌段共聚物胶束、单分子胶束和有机-无机杂化材料。
