Wang Zhi-Fang, Ding Qiong, Wang Kai-Xiang, Wu Chang-Min, Qu Yun-Huan, Zhao Xiao-Dong
Foreign Economic Cooperation Office, Ministry of Environmental Protection, Beijing 100035, China.
Huan Jing Ke Xue. 2012 Feb;33(2):574-9.
Based on the requirement of National Implementation Plan for the Stockholm Convention on Persistent Organic Pollutants (NIP), six industries including pulp and paper industry have been set as the priority key sectors to implement the best available technology and best environmental practice (BAT/BEP) within a specific time for UPOPs reduction. Non-wood pulping has always played important role in virgin pulp production in China, its elemental chlorinated bleaching process has been confirmed as main source of Dioxin emission for the sector. As the signature party of Stockholm Convention and long time existing country of non-wood pulping, identification of Dioxin emission situation is significant importance to China to committee the obligation of Stockholm Convention. The Dioxin concentrations in outflow water of bamboo, straw, reed, and bagasse pulping processes (chlorination alkaline extraction hypochlorite, CEH) are 41.8 pg x L(-1), 72.7 pg x L(-1), 7.46 pg x L(-1), and 19.7 pg x L(-1) respectively, which are all around the national waste water discharge standard (30 pg x L(-1)). But relevant data will easily exceed national standard while the limitation of unit water consumption for pulp making is decreased. So the application of best available techniques/best environmental practices (BAT/BEP) is very necessary to improve relevant mills up to the above standard, and proceed the sector meeting the national and international requirements for Dioxin emission. At the same time, the text calculates emission factors on bamboo, straw, reed and bagasse pulp making process through whole process monitoring, which will provide meaningful reference for increasing relevant factors in UNEP Toolkit.
根据《关于持久性有机污染物的斯德哥尔摩公约》国家实施计划(NIP)的要求,包括制浆造纸工业在内的六个行业已被确定为优先重点行业,要在特定时间内实施最佳可得技术和最佳环境实践(BAT/BEP)以减少非持久性有机污染物。非木浆制浆在中国原生浆生产中一直发挥着重要作用,其元素氯漂白工艺已被确认为该行业二恶英排放的主要来源。作为《斯德哥尔摩公约》的签署国和长期存在非木浆制浆的国家,识别二恶英排放情况对中国履行《斯德哥尔摩公约》的义务具有重要意义。竹、稻草、芦苇和甘蔗渣制浆工艺(氯化碱萃取次氯酸盐,CEH)流出水中的二恶英浓度分别为41.8 pg x L(-1)、72.7 pg x L(-1)、7.46 pg x L(-1)和19.7 pg x L(-1),均接近国家废水排放标准(30 pg x L(-1))。但当制浆单位水耗限值降低时,相关数据很容易超过国家标准。因此,应用最佳可得技术/最佳环境实践(BAT/BEP)对于提高相关工厂达到上述标准非常必要,并使该行业符合国家和国际二恶英排放要求。同时,本文通过全过程监测计算了竹、稻草、芦苇和甘蔗渣制浆过程的排放因子,这将为增加联合国环境规划署工具包中的相关因子提供有意义的参考。