Organisch-Chemisches Institut der Westfälischen Wilhelms-Universität Münster, Germany.
J Am Chem Soc. 2012 May 23;134(20):8298-301. doi: 10.1021/ja302631j. Epub 2012 May 15.
We report a uniquely high-yielding, general, and practical ortho bromination and iodination reaction of different classes of aromatic compounds. This reaction occurs by Rh(III)-catalyzed C-H bond activation methodology and is therefore the first example of the application of this cationic catalyst for C-Br and C-I bond formation.
我们报道了一种独特的、高产、通用且实用的芳香族化合物的邻位溴化和碘化反应。该反应通过 Rh(III)催化的 C-H 键活化方法进行，因此是该阳离子催化剂首次应用于 C-Br 和 C-I 键形成的实例。
