通过 Cu 催化与丙炔磷酸酯的直接偶联，简洁地制备（多氟芳基）丙二烯。
A concise access to (polyfluoroaryl)allenes by Cu-catalyzed direct coupling with propargyl phosphates.
机构信息
Department of Applied Chemistry, Faculty of Engineering, Osaka University , Suita, Osaka 565-0871, Japan.
出版信息
Org Lett. 2012 May 18;14(10):2586-9. doi: 10.1021/ol300886k. Epub 2012 May 2.
PMID:22551405
Abstract
A copper-based catalyst system for the direct coupling of polyfluoroarenes with propargyl phosphates has been developed. The catalysis can provide a rapid and concise access to (polyfluoroaryl)allenes, which can be important building blocks for the synthesis of fluorinated functional materials.
摘要
开发了一种用于多氟芳基与丙炔基磷酸酯直接偶联的铜基催化剂体系。该催化作用可以快速简洁地得到（多氟芳基）丙二烯，这是合成氟化功能材料的重要构建块。
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