铜催化的环境条件下唑类和多氟芳烃的直接亚磺酰化反应。
Copper-catalyzed direct sulfoximination of azoles and polyfluoroarenes under ambient conditions.
机构信息
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
出版信息
Org Lett. 2011 Feb 4;13(3):359-61. doi: 10.1021/ol102844q. Epub 2010 Dec 21.
PMID:21174416
Abstract
The direct dehydrogenative C-N coupling of azoles or polyfluoroarenes with N-H sulfoximines proceeds effectively in the presence of a copper catalyst at room temperature under air to afford the corresponding N-arylsulfoximines in good to high yields.
摘要
在室温下、空气氛围中、铜催化剂的存在下，唑类或多氟芳烃与 N-H 亚磺酰胺的直接脱氢 C-N 偶联反应能有效地进行，以良好至高产率得到相应的 N-芳基亚磺酰胺。
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