Li Shangkun, Lu Xiaofeng, Li Xiang, Xue Yanpeng, Zhang Chengcheng, Lei Junyu, Wang Ce
Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, PR China.
J Colloid Interface Sci. 2012 Jul 15;378(1):30-5. doi: 10.1016/j.jcis.2012.03.065. Epub 2012 Apr 13.
A reactive-template vapor phase polymerization method for the preparation of bamboo-like polypyrrole (PPy) nanotubes has been successfully demonstrated in this paper. Herein, electrospun V(2)O(5) nanofibers were chosen as templates to deposit PPy, which served as the oxidants as well. This method can provide the fabrication of PPy nanostructures more easily than conventional routes due to its independence of removing template, which is usually a complex and tedious experimental process. The application of bamboo-like PPy nanotubes for Cr(VI) ions removal in aqueous solution has been explored. The resulting bamboo-like PPy nanotubes exhibited much higher adsorption performance than traditional PPy nanoparticles.
本文成功展示了一种用于制备竹节状聚吡咯(PPy)纳米管的反应模板气相聚合方法。在此,选用静电纺丝的V(2)O(5)纳米纤维作为模板来沉积PPy,其同时也作为氧化剂。由于该方法无需去除模板,相较于传统路线,能更轻松地制备PPy纳米结构,而去除模板通常是一个复杂且繁琐的实验过程。本文还探索了竹节状PPy纳米管在水溶液中去除Cr(VI)离子的应用。所得的竹节状PPy纳米管表现出比传统PPy纳米颗粒更高的吸附性能。