金属有机膦作为不对称合成中的催化剂：一次回归之旅。
Metallic organophosphates as catalysts in asymmetric synthesis: a return journey.
机构信息
Departamento de Química Orgánica (Módulo 01), Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049-Madrid, Spain.
出版信息
Org Biomol Chem. 2012 Jul 14;10(26):5001-20. doi: 10.1039/c2ob25479d. Epub 2012 May 9.
PMID:22569751
Abstract
This perspective article provides a general overview of the most relevant topics in the applications of chiral metallic organophosphates. A brief introduction along with a historic comparative profile of the BINOL and phosphoric acid analogues are given. Next, a selection of the most outstanding uses of the catalysts according to the employed metal is presented.
摘要
这篇观点文章提供了手性金属有机膦酸盐应用中最相关主题的概述。简要介绍并对比了联二萘酚和磷酸类似物的历史发展。接下来，根据所使用的金属，选择了一些最杰出的催化剂应用。
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